Phase- and Reaction Equilibria

1. Introduction and repetition of fundamentals

2. Classification of phase diagrams

3. Calculation of phase equilibria with fugacity coefficients

3.1 The fugacity coefficient model for the chemical potential
3.2 Calculation of vapor-liquid equilibria with equations of state
3.3 Equilibrium between a gas mixture and a pure liquid

4. Calculation of phase equilibria with activity coefficients

4.1 The activity coefficient model for the chemical potential
4.2 Euler’s equation and the equation of Gibbs-Duhem
4.3 Models for molar excess free enthalpies
4.4 Calculation of vapor-liquid equilibria with activity coefficients
4.5 Determination of activity coefficients from measurements of phase equilibria
4.6 Equilibrium between a solution and a pure gas
4.7 Solubility of gases in liquids

5. Reaction equilibria with several linear independent reactions

6. Introduction to thermal separation processes

6.1 Absorption
6.2 Liquid-liquid equilibria
6.3 Stability and phase separation
6.4 Liquid-liquid extraction